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It has to do with the density differences between the center and edge of the sausage.It been very soundly proven that the rate of cooking has nothing to do with cupping, and while that the theory you wrote in your comment ("The outside of the pepperoni cooks faster than the inside, rendering the fat, causing the outside to shrink faster than the middle") seems to make sense (and in fact, it what I believed before I actually did research into it), it is in fact incorrect. Pepperoni that will curl will curl regardless of the rate at which you cook it. You can easily test this for yourself.EDIT: just repeating my comment below for better visibility as you seem intent on spreading misinformation.I expand to offer perhaps a bit more evidence that cupping is a result of the way in which meat is stuffed into the casing.As part of my research I spoke to experts from a few different pepperoni manufacturers.

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